In a recent blog I mentioned a research project just completed on a 30-year remeasurement of stone decay on St Paul’s cathedral in central London. A second paper looks at how this data might be used to model decay into the future (http://www.sciencedirect.com/science/article/pii/S1352231012007145 - you need to have an account to get access to the full paper in Atmospheric Environment). Modelling erosion rates into the future tends to use relationships derived from erosion data of small (50x50x10mm) stone tablets exposed in different environmental conditions. Using such data and regression analysis a statistical relationship can be derived between stone loss and changing environmental conditions. These relationships are often referred to as dose-response functions.
Two equations stand out – the Lipfert and the Tidblad et al. does response functions. Using these two equations for the decades 1980-2010, they predict an erosion rate of 15 and 12 microns per year as opposed to the measured losses on St Paul’s of 49 and 35 microns per year. The ratio between the measured and the dose-response erosion rates varies from 3.33 in the decade 1980-1990 to 2.75 in the decade 2000-2010, so fairly consistent. The difference between the two measures of decay may result from differences in what they are actually measuring. The dose-response function uses small stone tablets, exposed vertically in polluted environments. The weight loss of these tablets is measured and then converted to a loss across the whole surface of the tablet. The micro-erosion meter sites measure the loss of height of a number of points across the same surface on a decadal time scale. Both measures are changes in height but derived in different ways. What is important is that both methods indicate the same patterns of change in relation to declining sulphur dioxide levels. Both measures of erosion show a decline and both show it in the same direction and, by and large, in proportion to each other. Interestingly, when the dose-response functions are used to work out erosion on the cathedral since it was built the long-term erosion rate (as measured by lead fin heights relative to the stone surface) is only 2.5 times greater than that predicted by the does-response functions. This is a similar ratio, more or less, to those indicated over the last three decades.
The St Paul’s data does not imply that dose-response functions do not work – if anything it confirms the patterns in decay they indicate – but the St Paul’s data does suggest that using these dose-response functions to model decay into the future may require a correct function, equivalent to the ratio of about 2.5-2.75 to convert the losses to those that will be found on St Paul’s Cathedral.
Two equations stand out – the Lipfert and the Tidblad et al. does response functions. Using these two equations for the decades 1980-2010, they predict an erosion rate of 15 and 12 microns per year as opposed to the measured losses on St Paul’s of 49 and 35 microns per year. The ratio between the measured and the dose-response erosion rates varies from 3.33 in the decade 1980-1990 to 2.75 in the decade 2000-2010, so fairly consistent. The difference between the two measures of decay may result from differences in what they are actually measuring. The dose-response function uses small stone tablets, exposed vertically in polluted environments. The weight loss of these tablets is measured and then converted to a loss across the whole surface of the tablet. The micro-erosion meter sites measure the loss of height of a number of points across the same surface on a decadal time scale. Both measures are changes in height but derived in different ways. What is important is that both methods indicate the same patterns of change in relation to declining sulphur dioxide levels. Both measures of erosion show a decline and both show it in the same direction and, by and large, in proportion to each other. Interestingly, when the dose-response functions are used to work out erosion on the cathedral since it was built the long-term erosion rate (as measured by lead fin heights relative to the stone surface) is only 2.5 times greater than that predicted by the does-response functions. This is a similar ratio, more or less, to those indicated over the last three decades.
The St Paul’s data does not imply that dose-response functions do not work – if anything it confirms the patterns in decay they indicate – but the St Paul’s data does suggest that using these dose-response functions to model decay into the future may require a correct function, equivalent to the ratio of about 2.5-2.75 to convert the losses to those that will be found on St Paul’s Cathedral.
No comments:
Post a Comment